Tubes amps in general have big, wide and deep sound stage. They sound more life like, in other words, presence of sibilance and harshness is better controlled. Emotion aside, all most all tube amps have a better midrange clarity than similarly priced SS AMPS. They aren't the fastest or the most detailed in general. Tone mostly favour a warmer character.
These are general attributes, however sound characteristics of tubes amp considerably change with tube rolling. THATs for me is the most fun part. This is true for different tubes as well same tubes of different brands.
So, fun with tube is not entirely about the sound, it's the assortment of number of tubes and the different sound characteristics that they bring to the table.
For eg
A) My boyyurange EL 34 tube amp (with Mullards EL34 and Russian made 6HI preamp tube and Mullards GZ34 rectifier) sound absolutely liquid smooth in the midrange with deep, wide sound stage. In songs that compliments it's midrange heavy character, it sounded better to my ears than Marantz PM 8006 and Regards Elex Mark IV or any other sub 1.5L ss amps which I own. However, songs where treble and bass extension are necessary, you may not feel totally satisfied
B) Whereas, my Cayin A-88T with KT88 power tubes, sounds very different. Clear, precise and fast. Superb bass and treble extension. Midrange is less warm and smooth as compared to my boyyurange but the entire sound is very powerful, not just as a tube amp, but in general. Fun is, you can add that midrange smoothness by tube rolling.
I have heard PPL saying very different things about 300,B, 2A3 tubes as well. Never tried them
To sum it up, the midrange heavy character (or at the least the midrange clarity) and the ability to effect sound character by tube rolling make tube amp fun and entertaining and appealing to heart more than mind.