The Cables Should Not make any difference to the sound - Just Like a Firewire Cable - but the Siltech G-7 Firewire Cable for the dCS makes a huge difference...
Your firewire cable is part of the signal path. I might agree that it
should not make a difference at the digital level (although bad firewire cables are often the reason for firewire equipment not working) but I am not going to say "Utterly impossible."
There is probably some frustration on both sides of the network cable. Let me put an analogy that attempts to explain mine...
Person A can, and often does, drive a car. They are not a mechanic, but they are experienced at driving, know how the basic things work, and the necessary maintenance required.
Person B cannot drive and has no idea even how to name the components they would see under the bonnet of the car.
Person B says to person A, "Your car would go better if you change to different rubber on your accelerator pedal." Person A says, "Nonsense." Person B says, "How can you tell if you don't try? You have a closed mind. How can you deny what I say without experience?"
How can person A argue with person B (assuming he can be bothered). Person B may very well judge the smoothness and comfort of the car as a passenger, but he has no knowledge of the accelerator pedal technology.
Perhaps it is simply impossible for a rational argument to counter an irrational idea. Irrational does not admit of rational.
It is not quite the same, because many hifi people know a great deal about their systems and even the underlying technology, even though they often fall foul of the marketing people (a cable company I came across only recently asks, why do so many of the audiophile ideas and fads
not even exist on the professional side of the audio wall) by and large they (err...
we 
) do have a clue what they are doing.
So a hifi person, with experience of cables making a difference, even with experience of trying very many different combinations and getting just what they want out of it, encounters a new area of technology, and believes that they can apply the same idea and methods to it. That is the essential fallacy, because we can't. The only similarity between a length of analogue audio cable and a length of ethernet cable is that they can both be roughly called
pieces of wire. That's the end (ok, two ends) of it. That is the
rational of it. Even the increasing "Cat
n" numbers do not indicate increasing quality of signal, but only the speed at which the cable can operate. I wonder, in fact, if one can mess with the cables' composition and still
call it "Cat-
n?" I don't know that one, its a question for our more network-aware members.
But hey, try the alchemy. Some of those guys might even have fooled themselves that they got gold out of it.